Vermiculite refers to a mineral group and an industrial commodity (see part A for a description of both) and a mineral species. As a mineral species, the basic structure is a 2:1 layer [ideally Mg3(Si3Al)O10] regularly interstratified with a partially completed interlayer [Mg0.5(H2O)4], thus with an overall composition of Mg3(Si3Al)O10 . Mg0.5(H2O)4 in either space group Cc or C2/c. Vermiculites are generally alteration products of (trioctahedral) mica or chlorite and form in soils, with most vermiculite species being trioctahedral, although fine-grained soil varieties may be either dioctahedral or trioctahedral. The 2:1 layer has a net layer charge of -0.6 to -0.9 per formula unit, which is offset by the interlayer to achieve overall neutrality. Like smectite minerals, vermiculite has swelling capabilities. Stacking sequences depend on the H2O and cation configurations of the interlayer.
See intumescence in Part 1 of the Glossary.