Talc is a 2:1 layer silicate and ideally Mg3Si4O10(OH)2 with layers linked via van der Waals interactions (for a summary, see Evans and Guggenheim, 1988). Layer stacking is controlled by the avoidance of Si to Si electrostatic interactions across the interlayer to form a talc-1A polytype (where A = anorthic, older literature refers to this polytype as 1Tc). There are no six- or twelve-fold sites within the interlayer region as in the micas. The talc-2M polytype is poorly crystalline and rare. Talc is commonly near end-member compositions with more major substitutions of Fe2+ and more minor substitutions of Al and F, with trace substitutions of Mn, Ti, Cr, and Ni. The mineral willemseite is defined for Ni > Mg. Talc occurs in Mg-rich rocks in metamorphosed ultramafic rocks and siliceous dolomites. Talc has also been rarely reported from evaporites, limestones, in beach sands, low-temperature hydrothermal environments, and seafloor sediments.
Cf., kerolite, pyrophyllite, willemseite