Term: Alkylammonium organoclay monolayer

Alkylammonium organoclay monolayer

An interlamellar arrangement of one layer of alkylammonium cations with the C-C-C plane of the alkyl chains (n < 8) parallel to the (001) plane of the 2:1 layer to produce a characteristic 13.6-Å spacing of a phyllosilicate. The positively-charged end groups (e.g., NH3+) of the alkylammonium cations are attached to alternate siloxane surfaces in the interlayer. See Lagaly and Weiss (1975); Lagaly (1994).
Cf., alkylammonium layer charge method, organoclay