The surface charge of a phyllosilicate that relates to a net negative imbalance of charges originating from the silicate layers of the mineral. The magnitude or capacity for exchange (see cation exchange) is related to the size of the net negative charge that occurs within the (commonly, 2:1) layer. Cation exchange occurs where a solution containing the exchangeable cations forms a concentration gradient with the exchangeable cation of the mineral. The charge on the mineral is operationally related to the magnitude of the number of exchanged cations. The net negative charge is considered “permanent charge”, and this originates from either (or both) tetrahedral or octahedral solid solutions, changes in oxidation state of constituent cations in the layer, substitutions involving anions [e.g., O2- for (OH)-], and other possible factors.