See point of zero charge.
See point of zero charge.
Mineralogical term: an element found in small quantities in a mineral and not considered essential because it is not required for the structure to exist. A trace element is not quantitatively defined, but is generally considered to be <1wt. %. b) Medical/biological term: an element that occurs in animals or plants in small quantities and is required for physiological health. Cf., essential trace element
The phenomenon by which primary minerals in general, and chain silicates and phyllosilicates in particular, alter usually by weathering to secondary minerals through the direct incorporation and reuse of some part of the structure of the parent mineral. Products of transformation reactions are often pseudomorphous or alteromorphous after the primary reactant (parent) mineral, and often exhibit regular crystallographic and orientation relations with the reactant mineral.
See neoformation, inheritance
If an energetically unstable complex is present, TST states that a transitional state, or activated complex, occurs. This activated complex is a transitional state between the reactants and products, and is considered a hypothetical way to develop or explain the kinetics of, most commonly, a single-step (elementary) chemical reaction. The transitional state represents an energy barrier that must be overcome for mineral growth or dissolution.
Cf., molecularity
Describes a material that allows radiant energy to pass through it without significant adsorption, scatter or reflection.
Cf., opaque, translucent
A species of the chlorite mineral group that would have a trioctahedral 2:1 layer and a dioctahedral interlayer. There are no known chlorite structures of this type. Bailey (1988) described franklinfurnaceite, which has Ca between the 2:1 layer and the interlayer and thus is not a true chlorite, as tri,dioctahedral if the Ca is not considered.
Cf., dioctahedral chlorite, di,trioctahedral chlorite, trioctahedral chlorite, dioctahedral sheet, trioctahedral sheet
See crystal system.
Tridymite, a high temperature polymorph of SiO2, has many structural modifications and these are described by Heaney (1994). Ideally, the basic structure is comprised of sheets of hexagonal tetrahedral rings with alternate tetrahedra around a ring with apices pointing in opposite directions from adjacent tetrahedra. Adjacent tetrahedral sheets are related by a mirror plane to form channels normal to the sheets. Stacking of the sheets follow ABAB… stacking with A representing the initial sheet and B relating to its mirror image. Tridymite rarely occurs upon heating of SiO2 without the presence of a flux. Tridymite occurs as a devitrification phase of obsidian.
Cf., cristobalite, quartz
A trioctahedral member of the true mica group. The formula is KLi1.5Al1.5AlSi3O10F2. This formula does not represent an end-member composition. Trilithionite occurs in Li-rich, late stage, granitic pegmatites and aplites as 1M, 2M1 and 3T polytypes.
Low-charge smectite (e.g., SWy-1, SWy-2) treated with trimethylphenylammonium chloride (= phenyltrimethylammonium chloride) or trimethylammonium chloride yield organoclays that can effectively remove nonionic organic contaminants from water (Lee et al., 1990; Jaynes and Boyd 1990).