If an energetically unstable complex is present, TST states that a transitional state, or activated complex, occurs. This activated complex is a transitional state between the reactants and products, and is considered a hypothetical way to develop or explain the kinetics of, most commonly, a single-step (elementary) chemical reaction. The transitional state represents an energy barrier that must be overcome for mineral growth or dissolution.
Cf., molecularity

Describes a material that allows radiant energy to pass through it without significant adsorption, scatter or reflection.
Cf., opaque, translucent

A species of the chlorite mineral group that would have a trioctahedral 2:1 layer and a dioctahedral interlayer. There are no known chlorite structures of this type. Bailey (1988) described franklinfurnaceite, which has Ca between the 2:1 layer and the interlayer and thus is not a true chlorite, as tri,dioctahedral if the Ca is not considered.
Cf., dioctahedral chlorite, di,trioctahedral chlorite, trioctahedral chlorite, dioctahedral sheet, trioctahedral sheet

Tridymite, a high temperature polymorph of SiO₂, has many structural modifications and these are described by Heaney (1994). Ideally, the basic structure is comprised of sheets of hexagonal tetrahedral rings with alternate tetrahedra around a ring with apices pointing in opposite directions from adjacent tetrahedra. Adjacent tetrahedral sheets are related by a mirror plane to form channels normal to the sheets. Stacking of the sheets follow ABAB… stacking with A representing the initial sheet and B relating to its mirror image. Tridymite rarely occurs upon heating of SiO₂ without the presence of a flux. Tridymite occurs as a devitrification phase of obsidian.
Cf., cristobalite, quartz

A trioctahedral member of the true mica group. The formula is KLi_1.5Al_1.5AlSi₃O₁₀F₂. This formula does not represent an end-member composition. Trilithionite occurs in Li-rich, late stage, granitic pegmatites and aplites as 1M, 2M₁ and 3T polytypes.

Low-charge smectite (e.g., SWy-1, SWy-2) treated with trimethylphenylammonium chloride (= phenyltrimethylammonium chloride) or trimethylammonium chloride yield organoclays that can effectively remove nonionic organic contaminants from water (Lee et al., 1990; Jaynes and Boyd 1990).

A species of the chlorite mineral group with trioctahedral sheets only. This is the common form of chlorite.
Cf., dioctahedral chlorite, di,trioctahedral chlorite, trioctahedral sheet

A poorly defined material, possibly interstratified biotite and vermiculite.

In the ideal case, the smallest structural unit contains three octahedra. If two such sites are occupied with cations and one site is vacant, then the octahedral sheet is considered “dioctahedral”. If all three sites are occupied, the sheet is considered “trioctahedral”. (Quot Guggenheim et al., 2006; see also references therein). A trioctahedral sheet generally contains predominantly divalent cations.
Cf., dioctahedral sheet

An invalid term, previously used as a classification of the micas where the number of silicon atoms per formula unit is three per four tetrahedral sites.
See Rieder et al. (1998). Cf., mica, true mica, brittle mica, interlayer-deficient mica, group names.