W
Wodanite

An obsolete varietal term for biotite.

Wollastonite
Wonesite

A trioctahedral mica that shows interlayer deficiency. It is a series name (Rieder et al., 1998) with a generalized composition of Na0.5v0.5Mg2.5Al0.5(AlSi3)O10(OH)2, where = vacancy The formula indicates that it is not an end-member composition. Series names designate that additional research may be warranted.

Woodwardite
Wotanite

An obsolete varietal term for biotite.

Wulff rule

The Wulff rule or Gibbs-Curie-Wulff Theorem states that when the surface free energy of a crystal is minimized at equilibrium conditions, the perpendicular distance from a given crystal face to the center of the crystal divided by the surface free energy of that face is a constant for all faces of the crystal.

Wyoming bentonite

An obsolete term, see western bentonite.

Wyoming sodium bentonite

An obsolete term, see western bentonite.

Wyoming-type bentonite

An obsolete tern, see Western bentonite.

Wyoming-type montmorillonite

As described by Schultz (1969) based on chemical and thermal analysis, Wyoming-type montmorillonite is a type of montmorillonite characterized by a small net negative layer charge of about -0.35 to -0.85 per O20(OH)4, with tetrahedral substitutions causing from -0.15 to -0.50 of the total layer charge and specific thermal properties. Current nomenclature for montmorillonite is that it is an Al-rich, dioctahedral smectite with an ideal structural formula of (Al3.15Mg0.85)Si8O20(OH)4X0.85.nH2O with layer charge from primarily octahedral substitutions of Mg, whereas beidellite has a net layer charge that occurs from tetrahedral substitutions of Al, with an ideal structural formula of Al4.0(Si7.15Al0.85)O20(OH)4X0.85.nH2O. Although the structure of a mineral is important (not given here), thermal properties are not part of the definition. The Wyoming-type montmorillonite of Schultz (1969) is best described as an intermediate in the montmorillonite-beidellite series. The term ”Wyoming-type montmorillonite” is obsolete and should not be used.