See suspension.
See suspension.
A measure of the ability of a colloidal system (i.e., a gel or sol) to withstand a load (shear force) without loss of the high slurry viscosity and/or the mechanical elasticity, often measured with a rheometer and expressed in units of mass per area. The gel strength is a function of the inter-particle forces present in the solid-liquid system.
Cf., colloid, suspension, gel, sol
An industrial term for clay minerals (especially palygorskite, sepiolite, Na- or Na- exchanged montmorillonite, hectorite, and organoclay) having a high slurry viscosity at low percent solids when mixed with fluid. Such clay minerals form a colloid where the dispersed phase and the dispersion medium produce a semisolid material, similar to jelly. Industrial applications include thickening/suspension agents, adhesives, sealants, putties and glazing compounds. Jelling viscosity is typically measured on Fann or Brookfield viscometers. For aqueous applications and some fibrous clay minerals such as palygorskite, the gelling behavior and viscosity is enhanced by adding magnesium oxide or by extruding the slurry to align the needle-shaped crystallites. For montmorillonite, gelling behavior can be enhanced by soda ash treatments to increase the exchangeable Na-cation content and the swelling capacity of the clay mineral. For solvent-based applications, various smectites can be surface modified by quaternary-amine compounds to form organoclays that display superb gelling characteristics.
See colloid
A discredited term, a mixture of pimelite and Ni-rich serpentine.
The deliberate ingestion of (specifically) soil/clay; a form of pica.
Cf., pica
Geopolymers are inorganic binders used as cement substitutes. Geopolymers are made from activated (commonly heated or milled) silicate or aluminosilicate materials and are composed of poorly crystalline Al, Si networks. Commonly, thermally activated clay, i.e., metaclay (often metakaolin) is used, but geopolymers can be produced from feldspar, impure clay-rich interstratifications, waste product from coal combustion or metallic ores, fly ash or other ash material, iron oxides, or ground blast-furnace slag. These starting materials are mixed with an alkali or alkaline earth metal hydroxide solution such as KOH, NaOH or Ca(HO)2M (= alkali activation). The alkali or alkaline earth metal hydroxide solution dissolves Al, Si and alkali or alkaline earth elements. During the hardening process, the dissolved species polymerize to form a network characterized by short-range ordering. The name geopolymer is derived from “geo”, which refers to the origin of the precursor, and “polymer”, which refers to the linking of molecules in a repeated fashion.
Cf., alkali activation, blast-furnace slag, geopolymerization, glass, metaclay, metakaolin, thermal activation
The process of forming geopolymer cements. The gel-like mixture of the activated starting material (often metaclay) and the alkaline solution hardens upon drying by evaporation of water, forming a three dimensional inorganic network (geopolymer) by polymerization of Al and Si.
Cf., geopolymer, hardening, metaclay
Commercialized therapies using geologic materials, such as peloids, or processes, e.g., hot springs or mud baths.
Cf., peloid, pelotherapy
A thermodynamic state property useful to determine the spontaneity of a reaction within a system (without regard to the surroundings as is the case with entropy changes) and the direction of the reaction. The change in Gibbs energy, ΔG, is equal to ΔH – TΔS, where ΔH is the change in enthalpy (cal/mole), T is the absolute temperature (K), and ΔS is the change in entropy (cal deg-1 mole-1). A substance reacts if the change in Gibbs energy is negative going from the initial state to the final state. Gibbs energy is often referred to as Gibbs free energy.
See enthalpy, entropy, state function
See Gibbs energy.