Bonding of powdered material by solid-state reactions at temperatures lower than melting.
Bonding of powdered material by solid-state reactions at temperatures lower than melting.
Energy required to separate an ion an infinite distance from its equilibrium position in a crystal. In calculating an electrostatic site energy, the site energy is the sum of all the Coulombic and all the repulsive energies between the ion in the site and all neighbors in the unit cell.
See hydrotalcite group.
See microfabric, clay.
An obsolete term for glauconite.
A waste product from the iron-producing industry, sometimes used as a substitute for metaclay to produce geopolymers. Blast-furnace slag is produced when pure iron is separated from the silicate-containing byproducts. These byproducts are quenched rapidly in water to obtain a highly reactive material with a poorly crystalline to amorphous (glass-like) structure.
Cf., geopolymer, metaclay
See slaking.
The breakdown of large soil or clay material aggregates (typically >2-5 mm) or fine-grained sedimentary rock rich in clay into small particles (<0.25 mm) when rapidly immersed in water. Slaking occurs when aggregates are not sufficiently strong to withstand internal stresses caused by rapid water uptake into the pore structure or fabric of the aggregate. Internal stresses result from differential swelling of clay particles, trapped and escaping air from pores, rapid release of heat during wetting, and the mechanical action of moving water. Slaking is influenced by the presence of smectitic clays (either smectite, especially Na-montmorillonite, or interstratified clay with a smectite component) that shrink when dry and swell when wet. Organic matter often reduces slaking by binding the particles or by slowing the rate of surface wetting.
See blunging.
A group name for platy phyllosilicates of 2:1 layer and a layer charge of ~ -0.2 to -0.6 per formula unit. Generally for natural samples, the d(001) spacing is approximately 14.4-15.6 Å, although other spacing may occur depending on H2O retention and interlayer occupancy. The group is further divided into subgroups that are either trioctahedral (according to Bailey, 1980, this subgroup name is “saponite”) or dioctahedral (subgroup name of “montmorillonite”, according to Bailey, 1980), and these subgroups are further divided into mineral species based on chemical composition. Guggenheim et al. (2006) did not give subgroup names. Smectite minerals have large specific surface areas (10 – 700 m2/g) and exhibit a high expansion (swelling) capability in the presence of H2O. Smectite and vermiculite minerals are often referred to as “swelling” or “expandable” clay minerals. Cation-exchange capacity or solvation of polar molecules is large. Smectite is commonly a primary constituent of bentonite (see bentonite forrespective genesis information) and pelitic sediments (e.g., shales) and occurs in soils. Prior to circa 1975, the smectite group was called the montmorillonite-saponite group, but this nomenclature was abandoned because of the confusion between the use of the same name for both a group and species. Very early (Kerr and Hamilton, 1949), smectite was used as a term for fuller’s earth (initially), montmorillonite, and certain bentonitic clay deposits.
See “group names”.