Röttisite

A discredited name for material primarily containing pimelite.

Rubellan

A poorly defined material, possibly altered biotite or interlayer-deficient biotite, and/or vermiculite.

Rubification

A weathering process wherein minerals in a soil release iron which subsequently precipitates to form free iron oxides, such as hematite (red) and goethite (yellow brown), to produce reddening of a soil horizon.

Rumpfite

A poorly defined term, possibly for a Si-poor chlorite.

Saliotite

Saliotite is a regular interstratification (mixed layer) of cookeite-like and paragonite-like layers in a ratio of 1:1 (Goffé et al., 1994). The ideal chemical composition is Na0.5Li0.5Al3(Si3Al)O10(OH)5 and it occurs in high-pressure, low-temperature metamorphic rocks (estimated at 280-330oC, 8 kbar) in Andalusia, Spain.
Cf., interstratification

Sandbergite

An obsolete term for barian muscovite.

Sanidine
Saponite

Saponite is ideally (M+xy . nH2O)(Mg3-yR3+y )(Si4-xAlx)O10(OH)2 where M is the exchangeable cation in the interlayer (univalent example given here), R3+ are y trivalent cation substitutions in the octahedral site, x is the number of substitutions for Si by Al in the tetrahedral sites, and n is variable. Natural samples (Moore and Reynolds, 1997) may show < 0.66 Al tetrahedral atoms per asymmetric unit [O10(OH)2] to produce a large negative charge in the tetrahedral sheet which is balanced by positive charge in the octahedral sites (R3+ cations) and interlayer exchangeable (M) cations. Octahedral site vacancies may also occur (Newman and Brown, 1987). Suquet et al. (1975) determined that the two-layer hydrate structure (two planes of H2O) of a Na-saturated sample is C centered with a = 5.333, b = 9.233, c = 15.42 Å, β = 96.66 o. The sample approximates a Ia-2 polytype. The d(001) values of saponite commonly range from 13.5 (air dry) to 16.8 Å (ethylene glycol treatment). Dehydrated K-exchanged saponite shows a mica-like structure with stacking described as either a 1M or 3T structure. Saponite with a Mg-rich octahedral sheet is usually, but not limited to, a weathering product involving volcanic rocks (see Guggenheim, 2011 for a literature review of natural and synthetic saponite). Ferrian saponite (e.g., Kodama et al., 1988) with a composition of (M+0.61 . nH2O) (Mg1.39Fe3+0.85Al0.17Mn0.03) (Si3.49Al0.51) O10(OH)2 and ferrosaponite (Chukanov et al., 2003), (Ca0.31Na0.04K0.01 . 4H2O) (Fe2+1.54Mg0.85Fe3+0.45)Σ = 2.84 (Si2.87Al1.01Fe3+0.12) O9.67(OH)2.33, occur in a gabbro saprolite and as a hydrothermal mineral in basaltic pillow lavas, respectively.
Cf., smectite

Saprolite

A residual, sedentary, in situ regolith developed by chemical weathering of rocks, most often primary crystalline (igneous and metamorphic) bedrock. Saprolite preserves parent-rock textures in the form of abundant, predominantly argillaceous, and commonly pseudomorphous weathering products of individual primary minerals. Preservation of parent-rock mineral textures and fabrics in saprolite is often associated with high microporosity and may be a consequence of isovolumetric weathering. Saprolites are typically some meters thick but can be hundreds of meters thick.

Sarospatakite

An obsolete term for illite.