A high-temperature, orthorhombic (Pbcn) polymorph of enstatite. Protoenstatite has been thought to be unquenchable, and commonly transforms to clinoenstatite at low temperature in experiments. However, natural nanoparticle-size protoenstatite has been reported in gem quality “watermelon” sunstones from Oregon, U.S.A. and are apparently quenchable from high-temperature and high-pressure conditions as nanoparticles (Xu et al., 2017).