A trioctahedral member of the true mica group. The end-member formula is KMg3AlSi3O10(OH)2. Fe2+ for Mg substitution is common nearly to the Fe end member (annite). Mn and Ti and minor V and Cu substitution is less common. Octahedral vacancies are more prevalent in Fe-containing phlogopite. Phlogopite is defined as having <50% Fe substitution for Mg along the Mg/Fe join. When Fe and Mg content have not been determined, the series name, biotite, is appropriate. Tetrahedral Al substitution tends to be limited to <1.5 cations per formula unit (Fleet, 2003) and Fe3+ and Ti can occupy the tetrahedral site if there is a deficiency in Si. Phlogopite commonly occurs as the 1M and 1Md polytypes, although the 3T and 2M1 forms are less common.